Exfoliation method targets printable photonics, electronics

Scientists from the National University of Singapore (NUS) have unveiled a method to chemically exfoliate molybdenum disulfide crystals, a class of chalcogenide compounds, into high quality monolayer flakes, that they say offers higher yield and larger flake size than other known methods. The exfoliated flakes can be made into a printable solution, which can be applied in printable photonics and electronics.

This breakthrough, led by Loh Kian Ping, who heads the department of chemistry at the NUS Faculty of Science, and is also a principal investigator with the Graphene Research Center at the Faculty, has generic applicability to other 2D chalcogenides such as tungsten diselenide and titanium disulfide, and results in high yield exfoliation for all of these 2D materials.

The NUS team collaborated with scientists from the Ulsan National Institute of Science and Technology in Korea.

NUS chemists developed a method to chemically exfoliate molybdenum disulfide crystals into high quality monolayer flakes, offering higher yield and larger flake size than other methods.

Transition metal dichalcogenides, formed by a combination of chalcogens, such as sulphur or selenium, and transition metals, such as molybdenum or tungsten, have recently attracted great attention as the next generation of 2D materials due to their unique electronic and optical properties, for applications in optoelectronic devices such as thin film solars, photodetectors flexible logic circuits and sensors.

However, current processes of producing printable single layer chalcogenides take a long time and the yield is poor. The flakes produced are of submicron sizes, which make it challenging to isolate a single sheet for making electronic devices.

As most applications require clean and large-sized flakes, this pinpoints a clear need to explore new ways to make high quality single-layer transition metal dichalcogenides with high yield.

To address the production bottleneck, the NUS team explored the metal adducts of naphthalene. They prepared naphthalenide adducts of lithium, sodium and potassium, and compared the exfoliation efficiency and quality of molybdenum disulfide generated.

Using a two-step expansion and intercalation method, the researchers were able to produce high quality single-layer molybdenum disulfide sheets with unprecedentedly large flake size.

The researchers also demonstrated that the exfoliated molybdenum disulfide flakes can be made into a printable solution, and wafer-size films can be printed, as the good dispersion and high viscosity of the flakes render it highly suitable for inkjet printing.

In a comparative analysis, Zheng Jian, the first author of the paper, who is also a research fellow with the department of chemistry at NUS Faculty of Science, found that the alkali metal naphthalenide intercalation method applied possesses significant advantages in comparison to the conventional method.

Commenting on the significance of the findings, Loh said, "At present, there is a bottleneck in the development of solution-processed 2D chalcogenides. Our team has developed an alternative exfoliating agent using the organic salts of naphthalene and this new method is more efficient than previous solution-based methods. It can also be applied to other classes of 2D chalcogenides."

"Considering the versatility of this method, it may be adopted as the new benchmark in exfoliation chemistry of two-dimensional chalcogenides," he added.

The fast growing field of printed photonics, electronics and optoelectronics demands high material quality, precise material deposition, and application-specific optical, electrical, chemical and mechanical properties.

To further their research and to cater to the industry, Loh and his team will be looking at developing inks based on different types of 2D chalcogenides exfoliated by their novel method so as to produce printable optoelectronic devices. They will also be testing the optical non-linear properties of the flakes they have produced.